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Asymmetric Epoxidation Of Dihydronaphthalene With A Synthesized Jacobsen's Catalyst
Beginning of essay
Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen's
Chem 250 GG
Abstract. 1,2 diaminocyclohexane was reacted with L-(+)-tartaric acid to yield
(R,R)-1,2-diaminocyclohexane mono-(+)-tartrate salt. The tartrate salt was then
reacted with potassium carbonate and 3,5-di-tert-bu ....
Middle of essay
....y guide an enantiomeric catalytic reaction of industrial
and pharmacological importance. Very few reagents, let alone methods, are
known to be able to perform such a function, which indicates the truly
groundbreaking importance of Jacobsen's work.
Experimental Section
General Protocol. 99% L-(+)- Tartaric Acid, ethanol,
dihydronaphthalene and glacial acetic acid were obtained from the Aldrich
Chemical Company. 1,2 diaminocyclohexane (98% mix of cis/trans isomers) and
heptane were obtaine.... |
| Number of words: 2135 |
Approximate pages: 8 |
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